Semiconductors possess electrical conductivity that lies between the high conductivity of conductors and the low conductivity of insulators. By introducing impurities through a process known as doping, we can significantly enhance their conductivity. Based on the type of impurity added, doped semiconductors are categorized as P-type or N-type.
An intrinsic semiconductor is a pure semiconductor without any significant dopants—examples include silicon (Si) and germanium (Ge). When dopants are added, they become extrinsic semiconductors and are classified as either P-type or N-type.
An N-type semiconductor is created by doping a pure semiconductor with elements that have five valence electrons (pentavalent), such as phosphorus (P), arsenic (As), or antimony (Sb). These dopants provide an extra electron that becomes available for conduction.
A P-type semiconductor is formed by doping a pure semiconductor with elements having three valence electrons (trivalent), such as boron (B), aluminum (Al), or gallium (Ga). These create a deficiency of electrons, known as holes, which act as positive charge carriers.
Characteristic | P-type | N-type |
---|---|---|
Dopant Type | Trivalent (e.g., B, Al) | Pentavalent (e.g., P, As) |
Majority Carriers | Holes | Electrons |
Minority Carriers | Electrons | Holes |
Charge Movement | Due to hole migration | Due to electron flow |
Polarity | Positive-type (P-type) | Negative-type (N-type) |
Understanding the difference between P-type and N-type semiconductors is crucial in electronics and solid-state physics, as they form the building blocks of most modern electronic devices.